Unprecedented stereoselective synthesis of cyclopenta[b]benzofuran derivatives and their characterisation assisted by aligned media NMR and 13C chemical shift ab initio predictions.

نویسندگان

  • Martín J Riveira
  • Chakicherla Gayathri
  • Armando Navarro-Vázquez
  • Nicolay V Tsarevsky
  • Roberto R Gil
  • Mirta P Mischne
چکیده

A new approach to the synthesis of cyclopenta[b]benzofuran derivatives via reaction of 1,3-dicarbonyl compounds with α,β,γ,δ-unsaturated aldehydes is described. The constitution and configuration of the new products have been firmly established by means of residual dipolar couplings (RDCs) and ab initio (13)C NMR chemical shift predictions.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 9 9  شماره 

صفحات  -

تاریخ انتشار 2011